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IUPAC Nomenclature — JEE Previous Year Questions

Every IUPAC Nomenclature question asked in JEE Main and JEE Advanced across the last 186 papers — 40 questions, each with its correct answer. Free to read, no account needed.

Questions

40

Papers it appeared in

37/186

Appearance rate

20%

All 40 IUPAC Nomenclature questions

Most recent papers first.

Q1·ChemistrySingle correctJEE Main 2026
In IUPAC nomenclature, the correct order of decreasing priority of functional group is :
  1. (A)−CONH2, >C=O, −CHO, −NH2, −C≡C−-\mathrm{CONH_{2}},\ >\mathrm{C}=\mathrm{O},\ -\mathrm{CHO},\ -\mathrm{NH_{2}},\ -\mathrm{C}\equiv\mathrm{C}-−CONH2​, >C=O, −CHO, −NH2​, −C≡C−
  2. (B)−CONH2, −COOCH3, −CHO, −NH2, −OH-\mathrm{CONH_{2}},\ -\mathrm{COOCH_{3}},\ -\mathrm{CHO},\ -\mathrm{NH_{2}},\ -\mathrm{OH}−CONH2​, −COOCH3​, −CHO, −NH2​, −OH
  3. (C)−CONH2, −CHO, >C=O, −NH2, −C≡C−-\mathrm{CONH_{2}},\ -\mathrm{CHO},\ >\mathrm{C}=\mathrm{O},\ -\mathrm{NH_{2}},\ -\mathrm{C}\equiv\mathrm{C}-−CONH2​, −CHO, >C=O, −NH2​, −C≡C−
  4. (D)−CONH2, −CHO, −CN, −NH2, −C≡C−-\mathrm{CONH_{2}},\ -\mathrm{CHO},\ -\mathrm{CN},\ -\mathrm{NH_{2}},\ -\mathrm{C}\equiv\mathrm{C}-−CONH2​, −CHO, −CN, −NH2​, −C≡C−

Correct answer: (C)

Step-by-step solution →
Q2·ChemistrySingle correctJEE Main 2026
The IUPAC name of the following comopound is :
  1. (A)n-propyl-2-bromo-5-methylheptanoate
  2. (B)2-bromo-5-methylhexylpropanoate
  3. (C)2-bromo-5-methylpropanoate
  4. (D)n-propyl-1-bromo-4-methylhexanoate

Correct answer: (A)

Step-by-step solution →
Q3·ChemistrySingle correctJEE Main 2025
What is the correct IUPAC name of the following compound?
  1. (A)4-Ethyl-1-hydroxycyclopent-2-ene
  2. (B)1-Ethyl-3-hydroxycyclopent-2-ene
  3. (C)1-Ethylcyclopent-2-en-3-ol
  4. (D)4-Ethylcyclopent-2-en-1-ol

Correct answer: (D)

Step-by-step solution →
Q4·ChemistrySingle correctJEE Main 2025
Which of the following is the correct IUPAC name of the given organic compound (X) shown in the figure?
  1. (A)2-Bromo-2-methylbut-2-ene
  2. (B)3-Bromo-3-methylprop-2-ene
  3. (C)1-Bromo-2-methylbut-2-ene
  4. (D)4-Bromo-3-methylbut-2-ene

Correct answer: (C)

Step-by-step solution →
Q5·ChemistrySingle correctJEE Main 2025
Consider the following molecule (X). The structure of X is:
  1. (A)(1)
  2. (B)(2)
  3. (C)(3)
  4. (D)(4)

Correct answer: (B)

Step-by-step solution →
Q6·ChemistrySingle correctJEE Main 2025
The IUPAC name of the following compound is:
  1. (A)4-Hydroxyhept-1-en-6-yne
  2. (B)4-Hydroxyhept-6-en-1-yne
  3. (C)Hept-6-en-1-yn-4-ol
  4. (D)Hept-1-en-6-yn-4-ol

Correct answer: (D)

Step-by-step solution →
Q7·ChemistrySingle correctJEE Main 2025
What is the correct IUPAC name of the compound given below?
  1. (A)3-Bromo-2-hydroxy-5-nitrobenzoic acid
  2. (B)3-Bromo-4-hydroxy-1-nitrobenzoic acid
  3. (C)2-Hydroxy-3-bromo-5-nitrobenzoic acid
  4. (D)5-Nitro-3-bromo-2-hydroxybenzoic acid

Correct answer: (A)

Step-by-step solution →
Q8·ChemistrySingle correctJEE Main 2025
In 3,3-dimethylhex-1-ene-4-yne, there are ______ sp3sp^3sp3, ______ sp2sp^2sp2 and ______ spspsp hybridized carbon atoms respectively:
  1. (A)4, 2, 2
  2. (B)3, 3, 2
  3. (C)2, 4, 2
  4. (D)2, 2, 4

Correct answer: (A)

Step-by-step solution →
Q9·ChemistrySingle correctJEE Main 2025
Match List-I (Structure) with List-II (IUPAC Name). Choose the correct answer from the options given below:
List-I (Structure)List-II (IUPAC Name)
A.see figureI.4-Methylpent-1-ene
B.see figureII.3-Ethyl-5-methylheptane
C.see figureIII.4,4-Dimethylheptane
D.see figureIV.2-Methyl-1,3-pentadiene
  1. (A)(A)-(III), (B)-(II), (C)-(IV), (D)-(I)
  2. (B)(A)-(III), (B)-(II), (C)-(I), (D)-(IV)
  3. (C)(A)-(II), (B)-(III), (C)-(IV), (D)-(I)
  4. (D)(A)-(II), (B)-(III), (C)-(I), (D)-(IV)

Correct answer: (C)

Step-by-step solution →
Q10·ChemistrySingle correctJEE Main 2025
Total number of sigma (σ\sigmaσ) ______ and pi (π\piπ) ______ bonds respectively present in the hex-1-en-4-yne are:
  1. (A)13 and 3
  2. (B)11 and 3
  3. (C)13 and 5
  4. (D)14 and 3

Correct answer: (A)

Step-by-step solution →
Q11·ChemistryIntegerJEE Main 2025
The sum of sigma (σ\sigmaσ) and pi (π\piπ) bonds in Hex-1,3-dien-5-yne is ______.

Correct answer: 15

Step-by-step solution →
Q12·ChemistryIntegerJEE Main 2025
The hydrocarbon (X) with molar mass 80 g mol−1^{-1}−1 and 90% carbon has __________ degree of unsaturation.

Correct answer: 3

Step-by-step solution →
Q13·ChemistrySingle correctJEE Main 2025
In the given structure CH3-CO-CH=CH-CH2-C≡C-CH=CH-C≡NCH_3\text{-}CO\text{-}CH{=}CH\text{-}CH_2\text{-}C{\equiv}C\text{-}CH{=}CH\text{-}C{\equiv}NCH3​-CO-CH=CH-CH2​-C≡C-CH=CH-C≡N, the number of sp and sp2^22 hybridized carbon atoms present respectively are :
  1. (A)3 and 6
  2. (B)3 and 5
  3. (C)4 and 6
  4. (D)4 and 5

Correct answer: (B)

Step-by-step solution →
Q14·ChemistrySingle correctJEE Main 2025
The IUPAC name of the compound shown is:
  1. (A)1,2-Carboxy-5-methoxycarbonylhexane
  2. (B)Methyl-6-carboxy-2,5-dimethylhexanoate
  3. (C)Methyl-5-carboxy-2-methylhexanoate
  4. (D)6-Methoxycarbonyl-2,5-dimethylhexanoic acid

Correct answer: (D)

Step-by-step solution →
Q15·ChemistrySingle correctJEE Main 2024
Given below are two statements: Statement I: IUPAC name of Compound A (shown) is 4-chloro-1,3-dinitrobenzene. Statement II: IUPAC name of Compound B (shown) is 4-ethyl-2-methylaniline. In the light of the above statements, choose the most appropriate answer from the options given below:
  1. (A)Both Statement I and Statement II are correct
  2. (B)Statement I is incorrect but Statement II is correct
  3. (C)Statement I is correct but Statement II is incorrect
  4. (D)Both Statement I and Statement II are incorrect

Correct answer: (B)

Step-by-step solution →
Q16·ChemistrySingle correctJEE Main 2024
IUPAC name of the following hydrocarbon (X) is: CH3-CH(CH3)-CH2-CH2-CH(CH3)-CH(CH3)-CH2-CH3\text{CH}_3\text{-CH(CH}_3)\text{-CH}_2\text{-CH}_2\text{-CH(CH}_3)\text{-CH(CH}_3)\text{-CH}_2\text{-CH}_3CH3​-CH(CH3​)-CH2​-CH2​-CH(CH3​)-CH(CH3​)-CH2​-CH3​
  1. (A)2-Ethyl-3,6-dimethylheptane
  2. (B)2-Ethyl-2,6-diethylheptane
  3. (C)2,5,6-Trimethyloctane
  4. (D)3,4,7-Trimethyloctane

Correct answer: (C)

Step-by-step solution →
Q17·ChemistrySingle correctJEE Main 2024
The functional group present in sulphonic acid is:
  1. (A)−SO4H-SO_4H−SO4​H
  2. (B)−SO3H-SO_3H−SO3​H
  3. (C)−S(=O)−OH-S(=O)-OH−S(=O)−OH
  4. (D)−SO2−-SO_2-−SO2​−

Correct answer: (B)

Step-by-step solution →
Q18·ChemistrySingle correctJEE Main 2024
The correct IUPAC nomenclature for the compound shown below is:
  1. (A)2-carboxy-4-hydroxyhept-6-enal
  2. (B)2-carboxy-4-hydroxyhept-7-enal
  3. (C)2-formyl-4-hydroxyhept-6-enoic acid
  4. (D)2-formyl-4-hydroxyhept-7-enoic acid

Correct answer: (C)

Step-by-step solution →
Q19·ChemistryNumericalJEE Main 2024
The total number of 'sigma' and 'pi' bonds in 2-oxohex-4-ynoic acid is ______.

Correct answer: 18

Step-by-step solution →
Q20·ChemistrySingle correctJEE Main 2024
Identify structure of 2,3-dibromo-1-phenylpentane (from the structures shown in the figure).
  1. (A)(1)
  2. (B)(2)
  3. (C)(3)
  4. (D)(4)

Correct answer: (C)

Step-by-step solution →
Q21·ChemistrySingle correctJEE Main 2024
Given below are two statements: Statement I : IUPAC name of HO−CH2−(CH2)3−CH2−COCH3HO-CH_2-(CH_2)_3-CH_2-COCH_3HO−CH2​−(CH2​)3​−CH2​−COCH3​ is 7-hydroxyheptan-2-one. Statement II : 2-oxoheptan-7-ol is the correct IUPAC name for above compound. In the light of the above statements, choose the most appropriate answer from the options given below:
  1. (A)Statement I is correct but Statement II is incorrect.
  2. (B)Both Statement I and Statement II are incorrect.
  3. (C)Both Statement I and Statement II are correct.
  4. (D)Statement I is incorrect but Statement II is correct.

Correct answer: (A)

Step-by-step solution →
Q22·ChemistrySingle correctJEE Main 2024
Structure of 4-Methylpent-2-enal is:
  1. (A)(1)
  2. (B)(2)
  3. (C)(3)
  4. (D)(4)

Correct answer: (D)

Step-by-step solution →
Q23·ChemistrySingle correctJEE Main 2024
IUPAC name of following compound is: CH3−CH(NH2)−CH2−CNCH_3-CH(NH_2)-CH_2-CNCH3​−CH(NH2​)−CH2​−CN
  1. (A)2-Aminopentanenitrile
  2. (B)2-Aminobutanenitrile
  3. (C)3-Aminobutanenitrile
  4. (D)3-Aminopropanenitrile

Correct answer: (C)

Step-by-step solution →
Q24·ChemistrySingle correctJEE Main 2024
According to IUPAC system, the compound is named as:
  1. (A)Cyclohex-1-en-2-ol
  2. (B)1-Hydroxyhex-2-ene
  3. (C)Cyclohex-1-en-3-ol
  4. (D)Cyclohex-2-en-1-ol

Correct answer: (D)

Step-by-step solution →
Q25·ChemistrySingle correctJEE Main 2024
The bond line formula of HOCH(CN)2HOCH(CN)_2HOCH(CN)2​ is :
  1. (A)(1)
  2. (B)(2)
  3. (C)(3)
  4. (D)(4)

Correct answer: (D)

Step-by-step solution →
Q26·ChemistrySingle correctJEE Main 2023
The correct IUPAC nomenclature for the following compound is
  1. (A)5-Formyl-2-methylhexanoic acid
  2. (B)2-Methyl-5-oxohexanoic acid
  3. (C)2-Formyl-5-methylhexan-6-oic acid
  4. (D)5-Methyl-2-oxohexan-6-oic acid

Correct answer: (B)

Step-by-step solution →
Q27·ChemistrySingle correctJEE Main 2022
Correct structure of γ-methylcyclohexane carbaldehyde is :
  1. (A)(A)
  2. (B)(B)
  3. (C)(C)
  4. (D)(D)

Correct answer: (A)

Step-by-step solution →
Q28·ChemistrySingle correctJEE Main 2022
Match List-I with List-II. Choose the correct answer from the options given below :
  1. (A)(A) – (II), (B) – (I), (C) – (IV), (D) – (III)
  2. (B)(A) – (IV), (B) – (III), (C) – (I), (D) – (II)
  3. (C)(A) – (III), (B) – (IV), (C) – (I), (D) – (II)
  4. (D)(A) – (IV), (B) – (III), (C) – (II), (D) – (I)

Correct answer: (C)

Step-by-step solution →
Q29·ChemistrySingle correctJEE Main 2022
The correct decreasing order of priority of functional groups in naming an organic compound as per IUPAC system of nomenclature is :
  1. (A)—COOH > —CONH2CONH_{2}CONH2​ > —COCl > —CHO
  2. (B)—SO3HSO_{3}HSO3​H > —COCl > —CONH2CONH_{2}CONH2​ > —CN
  3. (C)—COOR > —COCl > —NH2NH_{2}NH2​ > >C = o
  4. (D)—COOH > —COOR > —CONH2CONH_{2}CONH2​ > —COCl

Correct answer: (B)

Step-by-step solution →
Q30·ChemistryNumericalJEE Main 2022
The number of sp3sp^{3}sp3 hybridised carbons in an acyclic neutral compound with molecular formula C4H5NC_{4}H_{5}NC4​H5​N is :

Correct answer: 1

Step-by-step solution →
Q31·ChemistrySingle correctJEE Main 2022
The correct IUPAC name of the following compound is :
  1. (A)4-methyl-2-nitro-5-oxohept-3-enal
  2. (B)4-methyl-5-oxo-2-nitrohept-3-enal
  3. (C)4-methyl-6-nitro-3-oxohept-4-enal
  4. (D)6-formyl-4-methyl-2-nitrohex-3-enal

Correct answer: (C)

Step-by-step solution →
Q32·ChemistrySingle correctJEE Main 2021
Choose the correct name for compound given below :
  1. (A)(4E)-5-Bromo-hex-4-en-2-yne
  2. (B)(2E)-2-Bromo-hex-4-yn-2-ene
  3. (C)(2E)-2-Bromo-hex-2-en-4-yne
  4. (D)(4E)-5-Bromo-hex-2-en-4-yne

Correct answer: (C)

Step-by-step solution →
Q33·ChemistryNumericalJEE Main 2021
The number of sigma bonds in H3C−C(H)=CH−C≡C−HH_3C-C(H)=CH-C\equiv C-HH3​C−C(H)=CH−C≡C−H is ____________________.

Correct answer: 10

Step-by-step solution →
Q34·ChemistryNumericalJEE Main 2021
The total number of C–C sigma bond/s in mesityl oxide (C6_{6}6​H10_{10}10​O) is____. (Round off to the Nearest Integer).

Correct answer: 5

Step-by-step solution →
Q35·ChemistrySingle correctJEE Advanced 2020
Which one of the following structures has the IUPAC name 3-ethynyl-2-hydroxy-4-methylhex-3-en-5-ynoic acid ?
  1. (A)(A)
  2. (B)(B)
  3. (C)(C)
  4. (D)(D)

Correct answer: (D)

Step-by-step solution →
Q36·ChemistrySingle correctJEE Main 2020
The IUPAC name of the following compound is [structure shown]
  1. (A)2-nitrogen-4-hydroxymethyl-5-amine benzaldehyde.
  2. (B)3-amino-4-hydroxymethyl 1-5-nitrobvenzaldehyde
  3. (C)5-amino-4hydroxymethyl-2-nitrobenzaldehyde
  4. (D)4-amino-2formyl-5hydroxymethyl nitrobenzene

Correct answer: (C)

Step-by-step solution →
Q37·ChemistrySingle correctJEE Main 2020
The IUPAC name of the following compound is:
  1. (A)4–Bromo–5–methylcyclopentanoic acid
  2. (B)4–Bromo–2–methylcyclopentane carboxylic acid
  3. (C)3–Bromo–5– methylcyclopentane carboxylic acid
  4. (D)5–Bromo–3–methylcyclopentanoic acid

Correct answer: (B)

Step-by-step solution →
Q38·ChemistrySingle correctJEE Main 2019
The IUPAC name of the following compound is :
  1. (A)3, 5-dimethyl-4-propylhept-1-en-6-yne
  2. (B)3-methyl-4-(1-methylprop-2-ynyl)-1-heptene
  3. (C)3-methyl-4-(3-methylprop-1-enyl)-1-heptyne
  4. (D)3, 5-dimethyl-4-propylhept-6-en-1-yne

Correct answer: (A)

Step-by-step solution →
Q39·ChemistrySingle correctJEE Main 2019
The correct IUPAC name of the following compound is
  1. (A)5-chloro-4-methyl-1-nitrobenzene
  2. (B)2-methyl-5-nitro-1-chlorobenzene
  3. (C)3-chloro-4-methyl-1-nitrobenzene
  4. (D)2-chloro-1-methyl-4-nitrobenzene

Correct answer: (D)

Step-by-step solution →
Q40·ChemistrySingle correctJEE Main 2019
The IUPAC name of the following compound is:
  1. (A)3-Hydroxy – 4 – methylpentaonic acid
  2. (B)4 – Methyl – 3 – hydroxypentanoic acid
  3. (C)2 – Methyl – 3 – hydroxylpentan-5-oic acid
  4. (D)4, 4 – Dimethyl – 3 – hydroxybutanoic acid

Correct answer: (A)

Step-by-step solution →

IUPAC Nomenclature — frequently asked

How many questions from IUPAC Nomenclature appear in JEE?

IUPAC Nomenclature has appeared in 37 of the last 186 JEE Main and JEE Advanced papers — about 20% of them — contributing 40 questions in total across those papers.

Is IUPAC Nomenclature an important chapter for JEE?

Judged by how often it is actually tested, it appears in roughly 20% of papers. Chapters above about 50% are effectively guaranteed to show up every session, so they repay thorough preparation; lower-frequency chapters are better treated as targeted revision.

Where do these IUPAC Nomenclature questions come from?

Every question is from an official JEE Main or JEE Advanced paper, transcribed from the original paper and tagged to this chapter. Answers follow the official answer key.

Other Chemistry chapters

  • Coordination Compounds 318
  • p-Block Elements 276
  • Redox Reactions and Electrochemistry 265
  • Chemical Bonding and Molecular Structure 207
  • d- and f-Block Elements 202
  • Aldehydes and Ketones 199
  • Equilibrium 199
  • Solutions 198

All 36 Chemistry chapters →

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